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Issue 30, 2012
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Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

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Abstract

Halide exchange from the species tBu3P(CO2)B(C6F5)2Cl 1 with Me3SiOSO2CF3 gave tBu3P(CO2)B(C6F5)2(OSO2CF3) 2. Similarly, Lewis acid exchange occurs in reactions of 1 with Al(C6F5)3 and [Cp2TiMe][B(C6F5)4] affording the products, tBu3P(CO2)Al(C6F5)33 and [tBu3P(CO2)TiCp2Cl][B(C6F5)4] 4.

Graphical abstract: Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

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Publication details

The article was received on 27 Jan 2012, accepted on 07 Feb 2012 and first published on 27 Feb 2012


Article type: Communication
DOI: 10.1039/C2DT30206C
Citation: Dalton Trans., 2012,41, 9016-9018
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    Exchange chemistry of tBu3P(CO2)B(C6F5)2Cl

    R. C. Neu, G. Ménard and D. W. Stephan, Dalton Trans., 2012, 41, 9016
    DOI: 10.1039/C2DT30206C

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