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Issue 17, 2012
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Chemo-switched chromatic, magnetic and structural changes with retention of molecular crystallinity, Ni(12aneS4)(BF4)2

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Abstract

The molecular crystal [Ni(12aneS4)](BF4)2 (12aneS4 = 1,4,7,10-tetrathiacyclododecane) displays the uncommon ability to retain its crystallinity on facile reversible hydration/dehydration without requiring polymeric bonding and despite the significant structural changes required. The flexibility of the 12aneS4 ring facilitates rearrangement of the complex in the solid state upon absorption of two equivalents of water, with the crystal structures showing a clear topotactic relationship. The well defined chromatic, structural and magnetic changes that are both highly sensitive and easily reversed makes this complex of interest as an environmentally responsive material and as a contrasting example to the commonly reported coordination polymers.

Graphical abstract: Chemo-switched chromatic, magnetic and structural changes with retention of molecular crystallinity, Ni(12aneS4)(BF4)2

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Publication details

The article was received on 21 Dec 2011, accepted on 25 Jan 2012 and first published on 06 Mar 2012


Article type: Paper
DOI: 10.1039/C2DT12468H
Citation: Dalton Trans., 2012,41, 5172-5176
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    Chemo-switched chromatic, magnetic and structural changes with retention of molecular crystallinity, Ni(12aneS4)(BF4)2

    A. J. Churchard, M. Derzsi, Z. Jagličić, A. Remhof and W. Grochala, Dalton Trans., 2012, 41, 5172
    DOI: 10.1039/C2DT12468H

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