The interplay of metal and supporting ligand in labile coordination to pincer complexes of Ag(i)†
Abstract
The bis(imino)pyridine scaffold provides support for the synthesis and characterization of unique Ag(I) pincer complexes [{ArNCPh}2(NPh)]Ag+(OTf)− (Ar = 2,5-tBu2C6H33; 2,6-iPr2C6H34). The bonding interactions between the