Issue 7, 2012

A porous metal–organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

Abstract

A novel mixed-ligand 3D metal–organic framework (MOF), {Zn2(TMTA)(bipy)0.5(H2O)2·NO3·2DMF·H2O}n (1) (H3TMTA = 4,4′,4′′-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid, bipy = 4,4′-bipyridine, DMF = dimethylformamide), was constructed based on bipy-pillared honeycomb bilayers and showed the unusual 2D→3D polycatenation of bilayers.

Graphical abstract: A porous metal–organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

Supplementary files

Article information

Article type
Communication
Submitted
10 Oct 2011
Accepted
06 Dec 2011
First published
22 Dec 2011

Dalton Trans., 2012,41, 1928-1930

A porous metal–organic framework (MOF) with unusual 2D→3D polycatenation based on honeycomb layers

X. Zhao, J. Dou, D. Sun, P. Cui, D. Sun and Q. Wu, Dalton Trans., 2012, 41, 1928 DOI: 10.1039/C2DT11898J

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