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Issue 8, 2013
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Linear trinuclear Zn(II)–Ce(III)–Zn(II) complex which behaves as a single-molecule magnet

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Abstract

Linear Zn(II)–Ce(III)–Zn(II) complex, which involves only one 4f electron as a spin source, behaves as an SMM. Easy-axis magnetic anisotropy for the ground 2F5/2 state of Ce(III) was achieved by a uni-axial crystal field, which is formed with four phenoxo oxygens as axial donors with the other five oxygens as equatorial donors.

Graphical abstract: Linear trinuclear Zn(ii)–Ce(iii)–Zn(ii) complex which behaves as a single-molecule magnet

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Publication details

The article was received on 24 Nov 2012, accepted on 21 Dec 2012 and first published on 03 Jan 2013


Article type: Communication
DOI: 10.1039/C2DT32812G
Citation: Dalton Trans., 2013,42, 2683-2686
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    Linear trinuclear Zn(II)–Ce(III)–Zn(II) complex which behaves as a single-molecule magnet

    S. Hino, M. Maeda, K. Yamashita, Y. Kataoka, M. Nakano, T. Yamamura, H. Nojiri, M. Kofu, O. Yamamuro and T. Kajiwara, Dalton Trans., 2013, 42, 2683
    DOI: 10.1039/C2DT32812G

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