A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

Andreas Nordheider; Tristram Chivers; Ramalingam Thirumoorthi; Kasun S. Athukorala Arachchige; Alexandra M. Z. Slawin; J. Derek Woollins; Ignacio Vargas-Baca

doi:10.1039/C2DT32716C

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Dalton Transactions

Issue 10, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

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A planar dianionic ditelluride and a cyclic tritelluride supported by P₂N₂ rings

Andreas Nordheider,^a^b Tristram Chivers,*^a Ramalingam Thirumoorthi,^a Kasun S. Athukorala Arachchige,^b Alexandra M. Z. Slawin,^b J. Derek Woollins^b and Ignacio Vargas-Baca^c

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Department of Chemistry, University of Calgary, Calgary, Canada T2N 1N4
E-mail: chivers@ucalgary.ca ;
Fax: +1 403-289-9488 ;
Tel: +1 403-220-5741

Department of Chemistry, University of St Andrews, St Andrews, UK

Department of Chemistry and Chemical Biology, McMaster University, Hamilton, Canada L8S 4M1

Dalton Trans., 2013,42, 3291-3294

DOI: 10.1039/C2DT32716C
Received 13 Nov 2012, Accepted 11 Dec 2012
First published online 13 Dec 2012

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Oxidation of alkali metal derivatives of [Te(^tBuN)P(μ-N^tBu)₂P(N^tBu)Te]²⁻ with I₂ produces the intermediate ditelluride dianion [Te(^tBuN)P(μ-N^tBu)₂P(N^tBu)Te]₂²⁻ with a planar PTeTeP conformation and, subsequently, the cyclic tritelluride [(^tBuN)P(μ-N^tBu)₂P(N^tBu)(μ-TeTeTe)].

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Andreas Nordheider
Tristram Chivers
Ramalingam Thirumoorthi
Kasun S. Athukorala Arachchige
Alexandra M. Z. Slawin
J. Derek Woollins
Ignacio Vargas-Baca

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A planar dianionic ditelluride and a cyclic tritelluride supported by P₂N₂ rings

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Dalton Transactions

A planar dianionic ditelluride and a cyclic tritelluride supported by P2N2 rings

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A planar dianionic ditelluride and a cyclic tritelluride supported by P₂N₂ rings