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Issue 5, 2013
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Expanding the coordination chemistry of donor-stabilized group-14 metalenes

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Abstract

The transformation of an amidinate germylene, equipped with just one accessible lone pair of electrons on the Ge atom, into a bidentate 4-electron donor κ2Ge,N-ligand, has been achieved for the first time, opening new doors to the non-carbene-like coordination chemistry of heavier carbene analogues.

Graphical abstract: Expanding the coordination chemistry of donor-stabilized group-14 metalenes

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Publication details

The article was received on 02 Oct 2012, accepted on 06 Nov 2012 and first published on 07 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT32654J
Citation: Dalton Trans., 2013,42, 1329-1332
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    Expanding the coordination chemistry of donor-stabilized group-14 metalenes

    J. A. Cabeza, P. García-Álvarez and D. Polo, Dalton Trans., 2013, 42, 1329
    DOI: 10.1039/C2DT32654J

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