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Issue 6, 2013
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The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−

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Abstract

The first example of a face-sharing fluoroaluminate anion, Al2F93−, is crystallographically determined in [C18MIm]3[Al2F9](CH2Cl2)1.754 (C18MIm+ = 1-methyl-3-octadecylimidazolium cation), and the geometry and bond properties therein are discussed with the aid of quantum chemical calculations.

Graphical abstract: The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−

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Publication details

The article was received on 02 Nov 2012, accepted on 30 Nov 2012 and first published on 30 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT32624H
Citation: Dalton Trans., 2013,42, 1965-1968
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    The first crystallographic example of a face-sharing fluoroaluminate anion Al2F93−

    F. Xu, K. Matsumoto and R. Hagiwara, Dalton Trans., 2013, 42, 1965
    DOI: 10.1039/C2DT32624H

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