The o-carborane–triarylborane dyad shows high fluoride ion affinity through the trigonal-planar boron center while degradation to nido-carborane leads to a turn-on fluorescence response toward fluoride.
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Dual sensing of fluoride ions by the o-carborane–triarylborane dyad
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a
Department of Chemistry, KAIST, Daejeon 305-701, Republic of Korea
E-mail: ykdo@kaist.ac.kr ;
Fax: +82 42 350 2810 ;
Tel: +82 42 350 2829
E-mail: ykdo@kaist.ac.kr ;
Fax: +82 42 350 2810 ;
Tel: +82 42 350 2829
b
Department of Chemistry and EHSRC, University of Ulsan, Ulsan 680-749, Republic of Korea
E-mail: lmh74@ulsan.ac.kr ;
Fax: +82 52 259 2348 ;
Tel: +82 52 259 2335
E-mail: lmh74@ulsan.ac.kr ;
Fax: +82 52 259 2348 ;
Tel: +82 52 259 2335
Dalton Trans., 2013,42, 2351-2354
DOI: 10.1039/C2DT32605A
Received 31 Oct 2012, Accepted 16 Nov 2012
First published online 16 Nov 2012
Dalton Transactions
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Crystal structure data
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