A redox-active dianionic N,O-phenolate-imidazolate/N,N-phenanthroline bridging ligand is used to form unique square-like neutral tetra-Cu(II) assemblies, the structural, magnetic, electronic and redox properties of which are herein described.
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Redox-switchable tetra-copper assembly of N,N-, N,O-phenolate-phenanthroimidazolate bridging ligands
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a
Department of Chemistry, Bar-Ilan University, Ramat Gan, Israel
E-mail: benisvl@mail.biu.ac.il ;
Fax: +972-3-7384053 ;
Tel: +972-3-7384599
E-mail: benisvl@mail.biu.ac.il ;
Fax: +972-3-7384053 ;
Tel: +972-3-7384599
b
Laboratoire de Spectrochimie Infrarouge et Raman, CNRS LASIR-UMR 8516, Bat C4 F-59655 Villeneuve d'Ascq Cedex, France
c
Department of Chemistry, University of Durham, South Road, Durham, UK
d
ICREA – Institut de Ciència de Materials de Barcelona (ICMAB-CSIC), Campus de la UAB, 08193 Bellaterra, Spain
Dalton Trans., 2013,42, 2358-2361
DOI: 10.1039/C2DT32585C
Received 29 Oct 2012, Accepted 19 Dec 2012
First published online 19 Dec 2012
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