The new complex Ru(NCO)2(IMes)(py)2(![[double bond, length as m-dash]](http://www.rsc.org/images/entities/char_e001.gif)
CHPh) is the first ruthenium metathesis initiator capable of fast, controlled living polymerization of functionalized norbornenes at room temperature, irrespective of monomer bulk.
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A Ru-isocyanate initiator for fast, living, precisely controlled ring-opening metathesis polymerization at ambient temperatures
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a
Department of Chemistry, Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Canada
E-mail: dfogg@uottawa.ca ;
Tel: +1 613-562-5800 ext. 6057
E-mail: dfogg@uottawa.ca ;
Tel: +1 613-562-5800 ext. 6057
b
Department of Chemistry, University of Alberta, Edmonton, Alberta, Canada
Dalton Trans., 2012,41, 14476-14479
DOI: 10.1039/C2DT32568C
Received 13 Sep 2012, Accepted 26 Oct 2012
First published online 29 Oct 2012
Dalton Transactions
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