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Issue 12, 2013
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Hydrothermal synthesis of an ortho-metallated Co(III) complex anchored by a carboxylate group with a selective oxidation catalytic property

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Abstract

An air-stable and water-tolerant ortho-metallated complex [Co(tfb)(bpy)2](NO3)·3H2O was obtained via hydrothermal synthesis. The mechanism for the formation of Co–C bond was studied using both DFT calculations and experimental analysis. This highly stable complex exhibits good catalytic performance for the selective oxidation of cyclohexane.

Graphical abstract: Hydrothermal synthesis of an ortho-metallated Co(iii) complex anchored by a carboxylate group with a selective oxidation catalytic property

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Publication details

The article was received on 17 Oct 2012, accepted on 17 Dec 2012 and first published on 17 Dec 2012


Article type: Paper
DOI: 10.1039/C2DT32468G
Citation: Dalton Trans., 2013,42, 4313-4318
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    Hydrothermal synthesis of an ortho-metallated Co(III) complex anchored by a carboxylate group with a selective oxidation catalytic property

    S. Zhang, W. Shi, J. Ma, Y. Zhang, Z. Zhang and P. Cheng, Dalton Trans., 2013, 42, 4313
    DOI: 10.1039/C2DT32468G

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