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Institute of Condensed Matter and Nanosciences, MOST – Inorganic Chemistry, Université Catholique de Louvain, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium
E-mail: damir.safin@ksu.ru
; Fax: +32 (0) 1047 2330
; Tel: +32 (0) 1047 2831
Dalton Trans., 2013,42, 1969-1972
DOI:
10.1039/C2DT32445H
Received
14 Oct 2012,
Accepted
03 Dec 2012
First published online
04 Dec 2012
A highly efficient Zn2+ “turn-on” fluorescent sensor, [4′-benzo-15-crown-5]NCH–(2-OH–C6H4) (HL), has been synthesized. In the presence of Zn(NO3)2, HL displays high selectivity and sensitive enhancement of fluorescence intensity in water with the formation of [ZnL2]. Addition of an equimolar amount of KNO3 to [ZnL2] leads to the formation of {[KZnL2]NO3}n.
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