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Reactivity of polynuclear palladium carboxylate complexes towards acetonitrile: synthesis and X-ray study of Pd2(C6H4-o-C([double bond, length as m-dash]NH)CH3)2(CH3CO2)2 and Pd5(CH3C([double bond, length as m-dash]N)OC([double bond, length as m-dash]N)CH3)(NO)(NO2)x(RCO2)7−x

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a
N.S. Kurnakov Institute of General and Inorganic Chemistry of Russian Academy of Sciences, 119991, Leninsky avenue, 31, Moscow, Russian Federation
E-mail: oshishilov@gmail.com;
Fax: +007 495 9541279 ;
Tel: +007 495 9554844
b
A.A. Baikov Institute of Metallurgy and Material Science of Russian Academy of Sciences, 119991, Leninsky avenue, 49, Moscow, Russian Federation
E-mail: nakhmadukllina@gmail.com;
Fax: +007 495 1358680 ;
Tel: +007 495 7181655
Dalton Trans., 2013,42, 3712-3720

DOI: 10.1039/C2DT32407E
Received 10 Oct 2012, Accepted 10 Dec 2012
First published online 11 Dec 2012
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