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Polyoxometalate–anatase TiO2 composites are introduced into the photoanode of dye-sensitized solar cells to retard the recombination and increase the electron lifetime
Department of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun, China
E-mail: wangeb889@nenu.edu.cn
; Fax: (+86) 431-85098787
Dalton Trans., 2013,42, 2691-2695
DOI:
10.1039/C2DT32403B
Received
10 Oct 2012,
Accepted
09 Dec 2012
First published online
11 Dec 2012
Polyoxometalate–TiO2 composites have been successfully introduced into the photoanode of dye-sensitized solar cells to reduce the recombination of the electrons, which results in a longer electron lifetime. The performance of the cells with the polyoxometalate-modified photoanode is better than the cell with a pure P25 photoanode. The effect of the polyoxometalate was studied by electrochemical impedance spectroscopy and open-circuit voltage decay measurement. The results show that the electron lifetime becomes longer following an increase in the amount of the polyoxometalate.
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