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Issue 7, 2013
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Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes

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Abstract

A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C–H bond activation.

Graphical abstract: Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

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Publication details

The article was received on 06 Oct 2012, accepted on 30 Nov 2012 and first published on 30 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT32368K
Citation: Dalton Trans., 2013,42, 2362-2365
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    Position-selective intramolecular aromatic C–H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(II) complexes

    K. Ogata, S. Inomata and S. Fukuzawa, Dalton Trans., 2013, 42, 2362
    DOI: 10.1039/C2DT32368K

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