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Department of Applied Chemistry, Institute of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan
E-mail: orgsynth@kc.chuo-u.ac.jp
; Fax: +81-3-3817-1895
; Tel: +81-3-3817-1916
Dalton Trans., 2013,42, 2362-2365
DOI:
10.1039/C2DT32368K
Received
06 Oct 2012,
Accepted
30 Nov 2012
First published online
30 Nov 2012
A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C–H bond activation.
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