A series of rare-earth zirconium chalcogenides Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) synthesized by using boron as the reducing reagent show unprecedented single-crystal's intrinsic voltage-dependent effects and order antiferromagnetically.
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Novel single-crystal's voltage-dependent effect and magnetic order of Ln2ZrQ5 (Ln = La, Sm, Gd; Q = S, Se) semiconductors
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State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China
E-mail: gcguo@fjirsm.ac.cn ;
Fax: +86 591 83714946
E-mail: gcguo@fjirsm.ac.cn ;
Fax: +86 591 83714946
Dalton Trans., 2013,42, 2679-2682
DOI: 10.1039/C2DT32321D
Received 02 Oct 2012, Accepted 18 Dec 2012
First published online 19 Dec 2012
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