Crystal structure of [Eu(CyMe4-BTBP)2κ2O,O′-(NO3)](NO3)2·n-C8H17OH and its structure in 1-octanol solution

Daniel Lundberg; Ingmar Persson; Christian Ekberg

doi:10.1039/C2DT32317F

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Dalton Transactions

Issue 11, 2013

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.806 48 Issues per Year Indexed in MEDLINE

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Crystal structure of [Eu(CyMe₄-BTBP)₂κ²O,O′-(NO₃)](NO₃)₂·n-C₈H₁₇OH and its structure in 1-octanol solution

Daniel Lundberg,*^a Ingmar Persson^a and Christian Ekberg^b

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Department of Chemistry, Uppsala BioCenter, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala, Sweden
E-mail: daniel.lundberg@slu.se ;
Tel: +46 18 671 549

Nuclear Chemistry/Industrial Materials Recycling, Chalmers University of Technology, SE-412 96 Göteborg, Sweden

Dalton Trans., 2013,42, 3767-3770

DOI: 10.1039/C2DT32317F
Received 02 Oct 2012, Accepted 24 Oct 2012
First published online 24 Oct 2012

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The structure of the [Eu(CyMe₄-BTBP)₂(NO₃)_n]⁽³⁻ⁿ⁾⁺ complex in 1-octanol solution and solid state has been determined by EXAFS and X-ray crystallography. The crystal structure shows that 1-octanol binds only to the europium(III)-coordinated BTBP molecules through weak van der Waals forces, making it the first indication of the role of the extraction solvent.