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Issue 11, 2013
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Crystal structure of [Eu(CyMe4-BTBP)2κ2O,O′-(NO3)](NO3)2·n-C8H17OH and its structure in 1-octanol solution

Daniel Lundberg,*a  Ingmar Perssona  and  Christian Ekbergb 
Author affiliations

* Corresponding authors

a Department of Chemistry, Uppsala BioCenter, Swedish University of Agricultural Sciences, P.O. Box 7015, SE-750 07 Uppsala, Sweden
E-mail: daniel.lundberg@slu.se
Tel: +46 18 671 549

b Nuclear Chemistry/Industrial Materials Recycling, Chalmers University of Technology, SE-412 96 Göteborg, Sweden

Abstract

The structure of the [Eu(CyMe4-BTBP)2(NO3)n](3−n)+ complex in 1-octanol solution and solid state has been determined by EXAFS and X-ray crystallography. The crystal structure shows that 1-octanol binds only to the europium(III)-coordinated BTBP molecules through weak van der Waals forces, making it the first indication of the role of the extraction solvent.

Graphical abstract: Crystal structure of [Eu(CyMe4-BTBP)2κ2O,O′-(NO3)](NO3)2·n-C8H17OH and its structure in 1-octanol solution

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Publication details

The article was received on 02 Oct 2012, accepted on 24 Oct 2012 and first published on 24 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT32317F
Citation: Dalton Trans., 2013,42, 3767-3770
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    Crystal structure of [Eu(CyMe4-BTBP)2κ2O,O′-(NO3)](NO3)2·n-C8H17OH and its structure in 1-octanol solution

    D. Lundberg, I. Persson and C. Ekberg, Dalton Trans., 2013, 42, 3767
    DOI: 10.1039/C2DT32317F

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