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Issue 2, 2013
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A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

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Abstract

Addition of [Mo2VO2(μ-O)(μ-S)(aq)]2+ linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W5} units logically in the self-assembly of a mixed oxide/sulphide {WVI72MoV60}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)2 and (μ-S)2 scenarios are known) and providing options to influence differently important capsule–substrate interactions.

Graphical abstract: A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

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Publication details

The article was received on 25 Sep 2012, accepted on 29 Oct 2012 and first published on 29 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT32247A
Citation: Dalton Trans., 2013,42, 330-333
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    A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

    C. Schäffer, A. M. Todea, H. Bögge, S. Floquet, E. Cadot, V. S. Korenev, V. P. Fedin, P. Gouzerh and A. Müller, Dalton Trans., 2013, 42, 330
    DOI: 10.1039/C2DT32247A

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