Two new oxomolybdenum(VI) complexes [(TpMoO2)2(μ-O)]·H2O (1) and (Tp4-IMoO2)2(μ-O) (2) were synthesized and characterized by elemental analysis, IR spectra, UV-Vis spectroscopy, powder X-ray diffraction, single-crystal X-ray diffraction and thermogravimetric analyses (TG). In addition, the catalytic performances of complexes 1 and 2 were studied firstly on the oxidation reaction of cyclohexane at room temperature.
Dalton Transactions
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