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Issue 43, 2012
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Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

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Abstract

With formate as ligand, two 1-D 3d–4f compounds (linear and zigzag) based on pyramidal {TbCu4} unit were obtained. Chair-like [(H2O)2(ClO4)2]2− clusters and μ514 bridging mode of formate were observed in the linear one which also displays slow relaxation of the magnetization.

Graphical abstract: Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

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Publication details

The article was received on 27 Jun 2012, accepted on 21 Sep 2012 and first published on 24 Sep 2012


Article type: Communication
DOI: 10.1039/C2DT32147E
Citation: Dalton Trans., 2012,41, 13264-13266
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    Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

    Z. Li, J. Yang, R. Liu, J. Zhang, S. Liu, J. Ni and C. Duan, Dalton Trans., 2012, 41, 13264
    DOI: 10.1039/C2DT32147E

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