Issue 43, 2012

Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

Abstract

With formate as ligand, two 1-D 3d–4f compounds (linear and zigzag) based on pyramidal {TbCu4} unit were obtained. Chair-like [(H2O)2(ClO4)2]2− clusters and μ514 bridging mode of formate were observed in the linear one which also displays slow relaxation of the magnetization.

Graphical abstract: Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

Supplementary files

Article information

Article type
Communication
Submitted
27 Jun 2012
Accepted
21 Sep 2012
First published
24 Sep 2012

Dalton Trans., 2012,41, 13264-13266

Two one-dimensional compounds based on pyramidal {TbCu4} units and formate ligand: chair-like [(H2O)2(ClO4)2]2− clusters and slow relaxation of magnetization

Z. Li, J. Yang, R. Liu, J. Zhang, S. Liu, J. Ni and C. Duan, Dalton Trans., 2012, 41, 13264 DOI: 10.1039/C2DT32147E

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