Issue 2, 2013

Combination between [B-α-SiW9O34] unit and triangular inorganic Ni6 core under hydrothermal conditions: from monomer to rare dimer with malposed dodeca-nickel centers

Abstract

The hydrothermal reactions of α-K4SiW12O40 with NiCl2·6H2O yielded two unprecedented silicotungstates containing a triangular inorganic Ni6 core. Furthermore, Na2[Ni63-OH)3(H2O)9SiW9O34]2·17H2O (1) presents a rare dimer, in which two SiW9 units sandwich double Ni6 cores by W–O–Ni linking instead of conventional Ni–O–Ni.

Graphical abstract: Combination between [B-α-SiW9O34] unit and triangular inorganic Ni6 core under hydrothermal conditions: from monomer to rare dimer with malposed dodeca-nickel centers

Supplementary files

Article information

Article type
Communication
Submitted
14 Sep 2012
Accepted
19 Oct 2012
First published
23 Oct 2012

Dalton Trans., 2013,42, 364-367

Combination between [B-α-SiW9O34] unit and triangular inorganic Ni6 core under hydrothermal conditions: from monomer to rare dimer with malposed dodeca-nickel centers

L. Yang, Y. Huo and J. Niu, Dalton Trans., 2013, 42, 364 DOI: 10.1039/C2DT32122J

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