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Issue 46, 2012
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Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

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We synthesised heteroleptic azadipyrrinato–dipyrrinato hybrid zinc(II) complex 1-Zn-2, by means of the stepwise coordination method. Homoleptic bis(azadipyrrinato)zinc(II) complex 1-Zn-1 was non-fluorescent, whereas 1-Zn-2 exhibited detectable fluorescence from azadipyrrinato ligand 1.

Graphical abstract: Fluorescent azadipyrrinato zinc(ii) complex: hybridisation with a dipyrrinato ligand

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The article was received on 04 Sep 2012, accepted on 27 Sep 2012 and first published on 03 Oct 2012

Article type: Communication
DOI: 10.1039/C2DT32039H
Citation: Dalton Trans., 2012,41, 14035-14037
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    Fluorescent azadipyrrinato zinc(II) complex: hybridisation with a dipyrrinato ligand

    R. Sakamoto, S. Kusaka, Y. Kitagawa, M. Kishida, M. Hayashi, Y. Takara, M. Tsuchiya, J. Kakinuma, T. Takeda, K. Hirata, T. Ogino, K. Kawahara, T. Yagi, S. Ikehira, T. Nakamura, M. Isomura, M. Toyama, S. Ichikawa, M. Okumura and H. Nishihara, Dalton Trans., 2012, 41, 14035
    DOI: 10.1039/C2DT32039H

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