Issue 1, 2013
From the journal:

Dalton Transactions

Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers†

Leila R. Hill,a   Thomas Just Sørensen,*ab   Octavia A. Blackburn,a   Asha Brown,a   Paul D. Beera  and  Stephen Faulkner*a  

* Corresponding authors

a Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: Stephen.Faulkner@chem.ox.ac.uk
Tel: +44 (0)1865 285148

b Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 København Ø, Denmark
E-mail: TJS@chem.ku.dk
Fax: +45 35 32 02 14
Tel: +45 35 32 02 13

Abstract

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1 : 1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.

Graphical abstract: Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers

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Article information

DOI
https://doi.org/10.1039/C2DT32009F
Article type
Communication
Submitted
31 Aug 2012
Accepted
08 Oct 2012
First published
09 Oct 2012

Dalton Trans., 2013,42, 67-70

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Self-assembly between dicarboxylate ions and binuclear europium complexes: moving to water—pH dependence and effects of buffers

L. R. Hill, T. J. Sørensen, O. A. Blackburn, A. Brown, P. D. Beer and S. Faulkner, Dalton Trans., 2013, 42, 67 DOI: 10.1039/C2DT32009F

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