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Issue 2, 2013
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Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands

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Abstract

The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.

Graphical abstract: Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

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Publication details

The article was received on 20 Aug 2012, accepted on 26 Sep 2012 and first published on 03 Oct 2012


Article type: Communication
DOI: 10.1039/C2DT31907A
Citation: Dalton Trans., 2013,42, 351-354
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    Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands

    M. Hernández-Juárez, M. Vaquero, E. Álvarez, V. Salazar and A. Suárez, Dalton Trans., 2013, 42, 351
    DOI: 10.1039/C2DT31907A

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