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Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5, 42184, Mineral de la Reforma, Hidalgo, Mexico
; Fax: +52 771 717200x6502
; Tel: +52 771 1550933
Instituto de Investigaciones Químicas (IIQ), Consejo Superior de Investigaciones Científicas and Universidad de Sevilla, Avda Américo Vespucio No. 49, 41092, Sevilla, Spain
; Fax: +34954460565
; Tel: +34 954489556
Dalton Trans., 2013,42, 351-354
20 Aug 2012,
26 Sep 2012
First published online
03 Oct 2012
The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.
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