Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

Anuradha Roy; Avanish K. Srivastava; Beer Singh; Dilip Shah; Timir Haran Mahato; Anchal Srivastava

doi:10.1039/C2DT31888A

Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

Anuradha Roy,^a Avanish K. Srivastava,^a Beer Singh,*^a Dilip Shah,^a Timir Haran Mahato^a and Anchal Srivastava^a

* Corresponding authors

^a Defence Research and Development Establishment, Jhansi Road, Gwalior 474 002, India
E-mail: beerbs5@rediffmail.com
Fax: +91-751-2233482
Tel: +91-9893040985

Abstract

The applicability of HKUST-1 for the degradation of sulfur mustard and sarin simulants was studied with and without coadsorbed water. Degradation was found to be via hydrolysis and dependent on the nucleophilic substitution reaction, vapour pressure and molecular diameter of the toxicants.

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Publication details

The article was received on 03 Jul 2012, accepted on 29 Aug 2012 and first published on 31 Aug 2012

Article type: Communication

DOI: 10.1039/C2DT31888A

Citation: Dalton Trans., 2012,41, 12346-12348

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Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

A. Roy, A. K. Srivastava, B. Singh, D. Shah, T. H. Mahato and A. Srivastava, Dalton Trans., 2012, 41, 12346
DOI: 10.1039/C2DT31888A
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Anuradha Roy
Avanish K. Srivastava
Beer Singh
Dilip Shah
Timir Haran Mahato
Anchal Srivastava

Dalton Transactions

Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

Abstract

Supplementary files

Publication details

Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

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