Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

Anuradha Roy; Avanish K. Srivastava; Beer Singh; Dilip Shah; Timir Haran Mahato; Anchal Srivastava

doi:10.1039/C2DT31888A

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Dalton Transactions

Issue 40, 2012

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

Anuradha Roy,^a Avanish K. Srivastava,^a Beer Singh,*^a Dilip Shah,^a Timir Haran Mahato^a and Anchal Srivastava^a

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Defence Research and Development Establishment, Jhansi Road, Gwalior 474 002, India
E-mail: beerbs5@rediffmail.com ;
Fax: +91-751-2233482 ;
Tel: +91-9893040985

Dalton Trans., 2012,41, 12346-12348

DOI: 10.1039/C2DT31888A
Received 03 Jul 2012, Accepted 29 Aug 2012
First published online 31 Aug 2012

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The applicability of HKUST-1 for the degradation of sulfur mustard and sarin simulants was studied with and without coadsorbed water. Degradation was found to be via hydrolysis and dependent on the nucleophilic substitution reaction, vapour pressure and molecular diameter of the toxicants.

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Anuradha Roy
Avanish K. Srivastava
Beer Singh
Dilip Shah
Timir Haran Mahato
Anchal Srivastava

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Kinetics of degradation of sulfur mustard and sarin simulants on HKUST-1 metal organic framework

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