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Reactions of Pd4(NO)4(CF3CO2)4 with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd6(μ-Cl)x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x were characterized by XRD analysis.
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