Jump to main content
Jump to site search

Issue 4, 2013
Previous Article Next Article

Incorporating different secondary building units of {Bi2}, {Bi8} and {Bi10} to construct diversity of luminescent bismuth–organic frameworks

Author affiliations

Abstract

Three new bismuth–organic compounds, namely, Bi(OH)(2,6-pdc)·H2O (1), Bi4(OH)4(2,6-pdc)4(H2O)3·H2O (2) and Bi5(OH)5(2,6-pdc)5(H2O)4·H2O (3) (2,6-H2pdc = pyridine-2,6-dicarboxylate) have been obtained by incorporating different Bi subunits as building blocks under hydrothermal conditions. Compound 1 contains dimeric {Bi2} units and these are further linked by 2,6-pdc2− ligands into a 2D net with 36 topology. Compounds 2–3 display 44 net topology by using linear {Bi8} and {Bi10} as secondary building units (SBUs), respectively. Compounds 1–3 display yellow and blue luminescence, respectively. Furthermore, the PXRD, TGA, UV-visible and IR spectra of 1–3 were also studied.

Graphical abstract: Incorporating different secondary building units of {Bi2}, {Bi8} and {Bi10} to construct diversity of luminescent bismuth–organic frameworks

Back to tab navigation

Supplementary files

Publication details

The article was received on 09 Aug 2012, accepted on 09 Oct 2012 and first published on 11 Oct 2012


Article type: Paper
DOI: 10.1039/C2DT31821K
Citation: Dalton Trans., 2013,42, 1088-1093
  •   Request permissions

    Incorporating different secondary building units of {Bi2}, {Bi8} and {Bi10} to construct diversity of luminescent bismuth–organic frameworks

    X. Zhang, H. Tian, G. Yan, Y. Su, Y. Feng and J. Cheng, Dalton Trans., 2013, 42, 1088
    DOI: 10.1039/C2DT31821K

Search articles by author

Spotlight

Advertisements