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National Engineering and Research Center for Advanced Polymer Processing Technology, Zhengzhou University, Henan 450001, P.R. China
Key Laboratory for Micro-Nano Energy Storage and Conversion Materials of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Henan 461000, P.R. China
; Fax: +86-374-2968784
; Tel: +86-374-2968784
Department of Chemistry, Zhengzhou University, Henan 450001, P.R. China
Dalton Trans., 2012,41, 12595-12600
05 Aug 2012,
18 Aug 2012
First published online
20 Aug 2012
Tubular nickel selenide (NiSe) crystals with hierarchical structures were successfully fabricated using a one-step solvothermal method in moderate conditions, in which ethylenediamine and ethylene glycol were used as the mixed solvent. The growth of hierarchical NiSe microtubes from NiSe microflakes was achieved without surfactants or other chemical additives by changing the reaction time. When the as-synthesized NiSe microtubes were employed as cathode materials for lithium-ion batteries, the initial discharge capacity of hierarchical NiSe microtubes reached 410.7 mAh g−1.
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