Ethylene/allyl monomer cooligomerization by nickel/phosphine–sulfonate catalysts

Shingo Ito; Yusuke Ota; Kyoko Nozaki

doi:10.1039/C2DT31771K

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Dalton Transactions

Issue 45, 2012

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Ethylene/allyl monomer cooligomerization by nickel/phosphine–sulfonate catalysts

Shingo Ito,^a Yusuke Ota^a and Kyoko Nozaki*^a

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Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: nozaki@chembio.t.u-tokyo.ac.jp ;
Fax: (+81) 3-5841-7263 ;
Tel: (+81) 3-5841-7261

Dalton Trans., 2012,41, 13807-13809

DOI: 10.1039/C2DT31771K
Received 02 Aug 2012, Accepted 21 Sep 2012
First published online 11 Oct 2012

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Abstract
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Nickel(II) complexes bearing a phosphine–sulfonate ligand, [(R₂PC₆H₄SO₃)NiMe(2,6-lutidine)] (R = cyclohexyl, 2-MeOC₆H₄, and 2-[2′,6′-(MeO)₂C₆H₃]C₆H₄, were synthesized and applied as catalysts for the cooligomerizations of ethylene and allyl monomers.

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