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Issue 4, 2013
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Trans [O[double bond, length as m-dash]ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

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Abstract

Three Re(V) N-heterocyclic carbene complexes [ReO(OH)(LMe)2][PF6]1.4[ReO4]0.6, [ReO(OH)(LiPr)2][PF6]1.4[ReO4]0.6 and [ReO(OH)(LBn)2][PF6]1.3[ReO4]0.7 (LMe = 1,1′-methylene-bis(3-methylimidazole-2-ylidene); LiPr = 1,1′-methylene-bis(3-isopropylimidazole-2-ylidene) and LBn = 1,1′-methylene-bis(3-benzylimidazole-2-ylidene)) with trans oxo and hydroxo at axial positions have been synthesized.

Graphical abstract: Trans [O [[double bond, length as m-dash]] ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

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Publication details

The article was received on 26 Jul 2012, accepted on 06 Nov 2012 and first published on 07 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT31681A
Citation: Dalton Trans., 2013,42, 871-873
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    Trans [O[double bond, length as m-dash]ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

    R. Lum, H. Zhang, W. Zhang, S. Bai, J. Zhao and T. S. A. Hor, Dalton Trans., 2013, 42, 871
    DOI: 10.1039/C2DT31681A

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