Jump to main content
Jump to site search

Issue 40, 2012
Previous Article Next Article

Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

Author affiliations

Abstract

Two metal–organic frameworks containing barium were synthesized hydrothermally and investigated for their catalytic properties. Ba2F2[O3SC2H4SO3] has barium fluoride layers linked by organic 1,2-ethanedisulfonate molecules. Ba[O3SC2H4SO3] has discrete barium centers arranged in layers and connected covalently by ethanedisulfonate bridges. Thermogravimetric analysis showed that Ba2F2[O3SC2H4SO3] is stable to ca. 325 °C and Ba[O3SC2H4SO3] to ca. 375 °C. These materials expand the metal–organic frameworks available for group II metals bound to organodisulfonate linkers and are potentially useful for a range of heterogeneous acid catalysis reactions.

Graphical abstract: Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 10 Jul 2012, accepted on 28 Aug 2012 and first published on 31 Aug 2012


Article type: Paper
DOI: 10.1039/C2DT31518A
Citation: Dalton Trans., 2012,41, 12630-12634
  •   Request permissions

    Solvothermal synthesis and characterization of two inorganic–organic hybrid materials based on barium

    Y. Abdollahian, J. L. Hauser, D. L. Rogow, A. G. Oliver and S. R. J. Oliver, Dalton Trans., 2012, 41, 12630
    DOI: 10.1039/C2DT31518A

Search articles by author