Jump to main content
Jump to site search

Issue 48, 2012
Previous Article Next Article

Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Author affiliations

Abstract

A new route to luminescent derivatives of androgenic steroids containing a ketone group in the 3- or 17-position has been developed. Reaction with the fac-Re(CO)3Cl complex of 3,3′-diamino-2,2′-bipyridine (complex 1) afforded a cyclic aminal product with different steroids. The rate of reaction and yield varies according to the conjugation or steric hindrance around the ketone group.

Graphical abstract: Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

Back to tab navigation

Supplementary files

Publication details

The article was received on 05 Jul 2012, accepted on 27 Sep 2012 and first published on 03 Oct 2012


Article type: Paper
DOI: 10.1039/C2DT31476B
Citation: Dalton Trans., 2012,41, 14690-14696
  •   Request permissions

    Luminescent rhenium fac-tricarbonyl-containing complexes of androgenic oxo-steroids

    S. Bullock, A. J. Hallett, L. P. Harding, J. J. Higginson, S. A. F. Piela, S. J. A. Pope and C. R. Rice, Dalton Trans., 2012, 41, 14690
    DOI: 10.1039/C2DT31476B

Search articles by author

Spotlight

Advertisements