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Issue 2, 2013
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An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

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Abstract

Two new photoluminescent magnesium-based coordination polymers, Mg(int)2·H2O (1) and Mg(nt)2 (2), were synthesized under solvothermal conditions. Structural analyses reveal that they have different 3,6-connected frameworks with rutile- and anatase-type topologies, respectively. Compound 1 remains stable after the removal of its guest molecules and it exhibits weak ferroelectric behavior.

Graphical abstract: An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

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Publication details

The article was received on 28 Jun 2012, accepted on 06 Nov 2012 and first published on 07 Nov 2012


Article type: Communication
DOI: 10.1039/C2DT31394D
Citation: Dalton Trans., 2013,42, 368-371
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    An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology

    T. Liu, D. Luo, D. Xu, H. Zeng and Z. Lin, Dalton Trans., 2013, 42, 368
    DOI: 10.1039/C2DT31394D

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