Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

Vassiliki N. Dokorou; Constantinos J. Milios; Athanassios C. Tsipis; Matti Haukka; Peter G. Weidler; Annie K. Powell; George E. Kostakis

doi:10.1039/C2DT31383A

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Dalton Transactions

Issue 40, 2012

The international journal for inorganic, organometallic and bioinorganic chemistry

Impact Factor 3.838 48 Issues per Year Indexed in MEDLINE

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Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H₂IBG) and divalent metal ions

Vassiliki N. Dokorou,^a^b Constantinos J. Milios,^c Athanassios C. Tsipis,^d Matti Haukka,^e Peter G. Weidler,^f Annie K. Powell^a^g and George E. Kostakis*^a

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Institute of Nanotechnology, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
E-mail: george.kostakis@kit.edu

X-Ray Unit, Department of Chemistry, University of Ioannina, 45110 Ioannina, Greece

Department of Chemistry, The University of Crete, Voutes, 71003, Herakleion, Greece

Laboratory of Inorganic and General Chemistry, Department of Chemistry, University of Ioannina, 451 10 Ioannina, Greece

University of Jyväskyla, Department of Chemistry, P.O. Box 35, FI-40014 University of Jyväskyla, Finland

Institute of Functional Interfaces, Karlsruhe Institute of Technology, Hermann-von-Helmholtz Platz 1, 76344 Eggenstein-Leopoldshafen, Germany

Institute of Inorganic Chemistry, Karlsruhe Institute of Technology, Engesserstrasse 15, 76131 Karlsruhe, Germany

Dalton Trans., 2012,41, 12501-12513

DOI: 10.1039/C2DT31383A
Received 27 Jun 2012, Accepted 10 Aug 2012
First published online 13 Aug 2012

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We present a systematic study of the complexation of the new pseudopeptidic ligand isophthaloylbisglycine (H₂IBG) with divalent metal ions of varying ionic radius. This work represents the initial employment of H₂IBG in the coordination chemistry of alkaline earth, 3d transition, Zn(II) and Cd(II) metal elements. Infrared, NMR, thermal, magnetic, adsorption and theoretical studies of these compounds are also discussed.

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Vassiliki N. Dokorou
Constantinos J. Milios
Athanassios C. Tsipis
Matti Haukka
Peter G. Weidler
Annie K. Powell
George E. Kostakis

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Dalton Transactions

Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H₂IBG) and divalent metal ions

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Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H2IBG) and divalent metal ions

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Pseudopeptidic ligands: exploring the self-assembly of isophthaloylbisglycine (H₂IBG) and divalent metal ions