Issue 4, 2013

Synthesis and X-ray structures of cyclometalated iridium complexes including the hydrides

Abstract

Cyclometalation of [Cp*IrCl2]2 with ketimine ligands generated very active catalysts for transfer hydrogenation of imines as well as reductive amination. The synthesis and X-ray diffraction structures of three such complexes are disclosed in this paper. The hydrides of two complexes, key intermediates in hydrogenation, have been isolated and their structures determined by X-ray diffraction as well.

Graphical abstract: Synthesis and X-ray structures of cyclometalated iridium complexes including the hydrides

Supplementary files

Article information

Article type
Paper
Submitted
26 Jun 2012
Accepted
20 Sep 2012
First published
20 Sep 2012

Dalton Trans., 2013,42, 935-940

Synthesis and X-ray structures of cyclometalated iridium complexes including the hydrides

C. Wang, H. T. Chen, J. Bacsa, C. R. A. Catlow and J. Xiao, Dalton Trans., 2013, 42, 935 DOI: 10.1039/C2DT31368E

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