A series of anthracene and acridine derivatives were hydrogenated under mild reaction conditions (80 °C, 3 bar of H₂) using the bis(dihydrogen) complex [RuH₂(η²-H₂)₂{P(C₆H₁₁)₃}₂] (1) as a catalyst precursor. The influence of a methyl substituent on the substrate was studied. In all our systems, hydrogenation was only observed at the external rings leading to the corresponding 4H- or 8H-derivatives of anthracene and acridine. Three complexes resulting from the η⁴(C,C)-coordination of the substrate to the unsaturated fragment [RuH₂{P(C₆H₁₁)₃}₂] were characterized. In the case of 9-methyl acridine, the corresponding complex [RuH₂(η⁴-C₁₄H₁₁N){P(C₆H₁₁)₃}₂] (4) turned out to be an active catalyst precursor leading to 1,2,3,4,5,6,7,8-octahydro-9-methylacridine as the sole product after 24 h. Regeneration of 1 from 4 supports the role of complex 4 in the catalytic cycle. Three hydrogenated products, 1,2,3,4-tetrahydroanthracene (4H-Anth), 1,2,3,4-tetrahydro-9-methylanthracene (4H-9-Me-Anth) and 1,2,3,4-tetrahydroacridine (4H-Acr), were characterized by X-ray diffraction.