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Issue 45, 2012
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Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

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Abstract

By adopting a ligand-based solid solution approach, the sulphonic acid functional group can be successfully incorporated into a porous coordination polymer with UiO-66 structure type. Zr6O4(OH)4(BDC-SO3H)1.1(BDC)4.9 possesses enhanced heat of adsorption for carbon dioxide and acetone compared to Zr6O4(OH)4(BDC)6.

Graphical abstract: Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

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Publication details

The article was received on 04 Jun 2012, accepted on 16 Jul 2012 and first published on 17 Jul 2012


Article type: Communication
DOI: 10.1039/C2DT31195J
Citation: Dalton Trans., 2012,41, 13791-13794
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    Ligand-based solid solution approach to stabilisation of sulphonic acid groups in porous coordination polymer Zr6O4(OH)4(BDC)6 (UiO-66)

    M. Lin Foo, S. Horike, T. Fukushima, Y. Hijikata, Y. Kubota, M. Takata and S. Kitagawa, Dalton Trans., 2012, 41, 13791
    DOI: 10.1039/C2DT31195J

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