The reaction of Co(NO3)2·6H2O and 3-benzoylpyridine with the low-spin iron(III) complex, H[FeIII(phen)(CN)4], in methanol gives rise to a cyanide-bridged heterobimetallic chain [{FeIII(phen)(CN)4}2CoII(3-bpe)2] (1) that exhibits intrachain ferromagnetic coupling and slow double magnetic relaxation.
Dalton Transactions
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