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Issue 35, 2012
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Copper(II) fluorophosphates

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Abstract

Eleven new copper fluorophosphate frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CuF2 HPF6 and monovalent metal fluorides as reactants. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra (n = 4–6). Analysis of these structures, in terms of the copper coordination environments and their linkage dimensionalities, shows that these features are dependent on fluoride-content of the reaction medium and, therefore, the level of fluoride ion incorporation into the product materials. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra.

Graphical abstract: Copper(ii) fluorophosphates

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Publication details

The article was received on 25 May 2012, accepted on 17 Jul 2012 and first published on 18 Jul 2012


Article type: Paper
DOI: 10.1039/C2DT31131C
Citation: Dalton Trans., 2012,41, 10845-10853
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    Copper(II) fluorophosphates

    E. R. Williams, S. A. Morris and M. T. Weller, Dalton Trans., 2012, 41, 10845
    DOI: 10.1039/C2DT31131C

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