Issue 36, 2012
From the journal:

Dalton Transactions

A tetrameric neptunyl(v) cluster supported by a Schiff base ligand†

Roy Copping,ab   Victor Mougel,a   Christophe Den Auwer,bc   Claude Berthon,b   Philippe Moisyb  and  Marinella Mazzanti*a  

* Corresponding authors

a Laboratoire de Reconnaissance Ionique et Chimie de Coordination, SCIB (UMR-E 3 CEA-UJF), INAC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 09, France
E-mail: marinella.mazzanti@cea.fr
Fax: +33 (4)38785090
Tel: +33 (4)38785090

b CEA, Nuclear Energy Division, Radiochemistry & Processes Department, 30207 Bagnols sur Cèze, France

c Nice Sophia Antipolis University, Chemistry Institute of Nice, 06108 Nice, France

Abstract

The first tetrameric cation–cation neptunyl(V) cluster, [{NpO2(salen)}4(μ8-K)2][K(18C6)Py]2, has been synthesized in non-aqueous solution from the reaction of [(NpO2Py5)(KI2Py2)]n with K2salen and its structure determined in the solid state and in solution where the complex retains its tetrameric form.

Graphical abstract: A tetrameric neptunyl(v) cluster supported by a Schiff base ligand

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Article information

DOI
https://doi.org/10.1039/C2DT31072D
Article type
Communication
Submitted
30 Mar 2012
Accepted
21 May 2012
First published
12 Jun 2012

Dalton Trans., 2012,41, 10900-10902

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A tetrameric neptunyl(V) cluster supported by a Schiff base ligand

R. Copping, V. Mougel, C. Den Auwer, C. Berthon, P. Moisy and M. Mazzanti, Dalton Trans., 2012, 41, 10900 DOI: 10.1039/C2DT31072D

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