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Issue 34, 2012
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Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

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Abstract

New coordination complexes of the neutral tripodal tetra-amine Me6TREN with tBu3Ga or tBu2Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an η1 or η2 mode, adding to previously reported η3 and η4 ligated examples.

Graphical abstract: Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

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The article was received on 16 May 2012, accepted on 20 Jun 2012 and first published on 22 Jun 2012


Article type: Communication
DOI: 10.1039/C2DT31061A
Citation: Dalton Trans., 2012,41, 10141-10144
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    Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

    T. Cadenbach, E. Hevia, A. R. Kennedy, R. E. Mulvey, J. Pickrell and S. D. Robertson, Dalton Trans., 2012, 41, 10141
    DOI: 10.1039/C2DT31061A

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