Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 35, 2012
Previous Article Next Article

The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

Author affiliations

Abstract

The ternary oxides Sb2MO6, Sb2M2O9, Sb4MO9 (M = Mo, W) and Sb2Mo3O12 were detected in the gas phase by means of mass spectrometry (MS). These gaseous oxides are reported for the first time. Thermodynamic data was obtained experimentally and confirmed by quantum chemical (QC) calculations. In addition, structural data on these molecules was obtained. The ionisation potentials (IP) were also determined both experimentally and theoretically.

Graphical abstract: The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 16 May 2012, accepted on 06 Jul 2012 and first published on 06 Jul 2012


Article type: Paper
DOI: 10.1039/C2DT31058A
Citation: Dalton Trans., 2012,41, 10769-10776
  •   Request permissions

    The formation and stability of molybdenum–antimony and tungsten–antimony ternary oxides Sb2MO6, Sb2M2O9, Sb2Mo3O12 and Sb4MO9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies

    E. Berezovskaya, E. Milke and M. Binnewies, Dalton Trans., 2012, 41, 10769
    DOI: 10.1039/C2DT31058A

Search articles by author