Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, P.R. China
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Dalton Trans., 2012,41, 13620-13625
13 May 2012,
19 Jun 2012
First published online
20 Jun 2012
The reaction of Mn(HCOO)2·2H2O, tBuSaoH2 (3,5-di-tert-butyl-salicylaldoxime) and sodium azide in isopropanol leads to [NaMn3(tBuSao)6] (1). Its structure can be described as a linear trinuclear cluster bridged by oximato ligands. Magnetic investigation revealed that the ferromagnetic coupling interaction is dominant in 1 leading to a ground-state spin ST = 5. 1 shows single-molecule magnet behaviour under zero or 1 kOe dc field with energy barrier Ueff 10 K.
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