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Issue 38, 2012
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Two hybrid polyoxometalate-pillared metal–organic frameworks

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Two polyoxometalate-pillared 3D compounds, {Cu5(2-ptz)6(H2O)4(SiW12O40)}·4H2O 1 and {Cu9(2-ptz)12(H2O)6(PMo12O40)2}·H2O 2 (2-ptz = 5-(2-pyridyl)tetrazole) have been constructed based on different polyoxometalate anions, and copper–organic coordination polymer sheets by a hydrothermal method. Magnetic investigations reveal that both 1 and 2 exhibit antiferromagnetic coupling between the CuII ions. Structural studies show the compound 1 exhibits a typical pcu-type net with the Schälfli symbol of {412·63}, and that compound 2 is a (3,4,6)-connected framework with novel {44·610·10}{63}2{65·8} topology which has not been reported to date.

Graphical abstract: Two hybrid polyoxometalate-pillared metal–organic frameworks

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Publication details

The article was received on 27 Apr 2012, accepted on 22 Jun 2012 and first published on 25 Jun 2012

Article type: Paper
DOI: 10.1039/C2DT30920C
Citation: Dalton Trans., 2012,41, 11783-11787
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    Two hybrid polyoxometalate-pillared metal–organic frameworks

    X. Wu, Q. Zhang, X. Kuang, W. Yang, R. Yu and C. Lu, Dalton Trans., 2012, 41, 11783
    DOI: 10.1039/C2DT30920C

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