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Formation of stable iron/cobalt NHC complexes via unexpected ring opening and in situ generation of a tridentate ligand

Gao-Feng Wang,a   Xiao-Jiao Song,a   Fei Chen,a   Yi-Zhi Li,a   Xue-Tai Chen*a and   Zi-Ling Xue*b  
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a
State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China
E-mail: xtchen@netra.nju.edu.cn;
Fax: +86 25 83314502
b
Department of Chemistry, University of Tennessee, Knoxville, USA
E-mail: xue@utk.edu;
Fax: +18659743454
Dalton Trans., 2012,41, 10919-10922

DOI: 10.1039/C2DT30894K
Received 24 Apr 2012, Accepted 30 Jul 2012
First published online 01 Aug 2012
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