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Issue 34, 2012
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Unique in situ reduction of copper(II) forming an interesting photoluminescent stair-polymer of copper(I) with a Cu2S2 core

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Abstract

A novel thiocyanate bridged one-dimensional copper(I) polymer, [CuL(μ-1,1,3-SCN)]n (L = 5,6-diphenyl-2,3-dihydropyrazine), has been synthesized and characterized by X-ray crystallography. The complex features a copper(I) stair-step polymeric coordination network with a Cu2S2 core. The complex shows strong fluorescence.

Graphical abstract: Unique in situ reduction of copper(ii) forming an interesting photoluminescent stair-polymer of copper(i) with a Cu2S2 core

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Publication details

The article was received on 21 Apr 2012, accepted on 02 Jul 2012 and first published on 03 Jul 2012


Article type: Communication
DOI: 10.1039/C2DT30871A
Citation: Dalton Trans., 2012,41, 10145-10149
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    Unique in situ reduction of copper(II) forming an interesting photoluminescent stair-polymer of copper(I) with a Cu2S2 core

    S. Jana, P. Bhowmik and S. Chattopadhyay, Dalton Trans., 2012, 41, 10145
    DOI: 10.1039/C2DT30871A

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