Two homochiral coordination polymers, namely, [YbIII3MnIII6(L)6(μ2-OMe)6(isonicotinate)2(HOMe)2][YbIII3MnIII6(L)6(μ2-OMe)6(isonicotinate)2(HOMe)4](NO3)2·6MeOH·12H2O (5) (H3L = (S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid) and [YbIII3MnIII6Na(L)6(μ2-OMe)6(OOCH)3]I·17H2O (6), have been constructed by utilizing a stable enantiopure [YbIII3MnIII6(L)6(μ2-OMe)6]3+ (Yb3Mn6) cluster as a precursor.
Dalton Transactions
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