Expansion of a Schiff-base polypyrrolic macrocycle allows the formation of a binuclear uranyl complex with co-linear uranyl ions and a very short oxo–oxo distance.
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Co-linear, double-uranyl coordination by an expanded Schiff-base polypyrrole macrocycle
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a
EaStCHEM School of Chemistry, University of Edinburgh, The King's Buildings, Edinburgh, UK
E-mail: polly.arnold@ed.ac.uk
E-mail: polly.arnold@ed.ac.uk
b
Department of Chemistry, University of Manitoba, Winnipeg, Canada
c
Key Laboratory of Functional Inorganic Material Chemistry of Education Ministry, School of Chemistry and Materials Science, Heilongjiang University, Harbin, China 150080
Dalton Trans., 2012,41, 6595-6597
DOI: 10.1039/C2DT30658A
Received 22 Feb 2012, Accepted 27 Mar 2012
First published online 30 Apr 2012
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